4.7 Article

Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids

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CHEMICAL COMMUNICATIONS
卷 47, 期 38, 页码 10791-10793

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12359a

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  1. Ministry of Education, Culture, Sports, Science, and Technology of Japan
  2. Grants-in-Aid for Scientific Research [22245017] Funding Source: KAKEN

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We have succeeded in the allylation of aromatic and olefinic C-H bonds of benzoic and acrylic acids using a rhenium catalyst,Re-2(CO)(10). In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur.

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