期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 46, 页码 8806-8808出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03154b
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资金
- Natural Science Foundation of China [20633020]
- Basic Research Program of China [2009CB220009]
- Program for Innovative Research Team of Liaoning Province [2006T025]
- Swedish Energy Agency
- Swedish Research Council
- K & A Wallenberg Foundation
Among three noble-metal-free molecular devices (1-3) containing a porphyrin photosensitizer and a cobaloxime catalyst, the one with a zinc porphyrin unit displayed apparently higher efficiency for photoinduced H-2 production than complex 2 with a magnesium porphyrin and 3 with a free-base porphyrin, possibly due to the formation of a TEA center dot center dot center dot ZnPor-Co triad in solution.
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