期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 19, 页码 3372-3374出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c001703e
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资金
- EPSRC
- EPSRC [EP/E001629/1, EP/E01819X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/E01819X/1, EP/E001629/1] Funding Source: researchfish
During asymmetric cyanohydrin synthesis catalysed by vanadium(V) oxo(salen) complexes, the catalysts are reduced to vanadium(IV) oxo(salen) as determined by EPR spectroscopy; the reducing agent is cyanide which is oxidised to cyanogen via a non-radical mechanism.
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