期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 41, 页码 7825-7827出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02015j
关键词
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资金
- Ministerio de Ciencia e Innovacion, Gobierno de Espana for the concession of a Ramon y Cajal contract [RYC-2009-04199]
- Ministerio de Educacion y Ciencia [CTQ2007-65754/PPQ]
- Ministerio de Ciencia e nnovacion [CTQ2008-01330/BQU]
- Consejeria de Educacion y Ciencia, Junta de Andalucia [P07-FQM-02695, P09-FQM-4781]
- FEDER
A synergetic Fe-Al effect in Fe2O3 nanoparticles supported on mesoporous aluminosilicates compared to pure siliceous silicates has been demonstrated, for the first time, by a remarkably superior catalytic activity of the former in the microwave-assisted selective oxidation of benzyl alcohol to benzaldehyde. This significant finding, that also deeply influences the acidity of the materials (increasing total and particularly Lewis acidity), can have important consequences in the improved efficiency of these systems in related oxidations as well as in acid catalysed processes.
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