期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 23, 页码 4196-4198出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c002767g
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资金
- U.S. Department of Energy [DE-FC36-07GO17033]
- U.S. Defense Logistics Agency [N00164-07-P-1300]
- U.S. National Science Foundation [CHE-0449634]
- National Science Foundation/Department of Energy [CHE-0535644]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
A NbO-type metal-organic framework, PCN-46, was constructed based on a polyyne-coupled di-isophthalate linker formed in situ. Its lasting porosity was confirmed by N(2) adsorption isotherm, and its H(2), CH(4) and CO(2) adsorption capacity was examined at 77 K and 298 K over a wide pressure range (0-110 bar).
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