4.7 Article

An unusual case of symmetry-preserving isomerism

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 8, 页码 1329-1331

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/b920995f

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资金

  1. US Department of Energy [DE-FC36-07GO17033, BES DE-FG02-98ER45701]
  2. US National Science Foundation [CHE-0449634]
  3. Argonne National Laboratory

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Two isomeric phases of the NbO-type structure have been discovered: PCN-16 (alpha phase) and PCN-16' (beta phase), and gas sorption studies revealed that the alpha phase possesses a larger surface area, leading to higher hydrogen and methane storage capacity as compared with the beta phase.

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