期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 32, 页码 5963-5965出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01181a
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资金
- Department of Chemistry, Case Western Reserve University
- Deutsche Forschungs gemeinschaft (DFG)
The excited-state dynamics of 4-thiothymidine in the ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide, is revealed. Branching of the initial excited-state population results in efficient intersystem crossing to the triplet manifold with a rate constant of 1.6 x 10(12) s(-1) and close to unity triplet yield after UVA excitation at 340 or 360 nm.
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