4.7 Article

Mechanism of visible-light photoisomerization of a rhenium(I) carbonyl-diimine complex

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 43, 页码 8225-8227

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02661a

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  1. European COST Action [D35]
  2. Egide/DAAD Procope [20139VE]

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The mechanism of photoisomerization of a Re(I) carbonyl-diimine complex under visible-light irradiation is deciphered by means of ab initio calculations. By highlighting the key role of triplet states as well as spin-orbit and vibronic couplings, we provide a clear picture of this complicated multi-step process.

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