4.7 Article

Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 39, 页码 7352-7354

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02771e

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资金

  1. US Department of Energy [DE-SC0001015]
  2. National Science Foundation [CHE-0930079, CHE-0911207]
  3. National Science Foundation/Department of Energy [CHE-0535644]
  4. US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]

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A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.

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