期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 29, 页码 5373-5375出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01042a
关键词
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资金
- National Natural Science Foundation of China [20772037]
- Science and Technology Planning Project of Guangdong Province [2006A 10902002]
- US Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [KC020105-FWP12152]
- DOE [DE-AC05-76RL01830]
- [9251063101000006]
- [06025033]
Two novel cadmium-organic frameworks containing achiral helical nanotubular channels, [Cd(HImDC)(S)](n) (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.
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