期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 33, 页码 6141-6143出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01105c
关键词
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For the first time, an open-framework oxysalt of trivalent vanadium is demonstrated, prepared from a single tetravalent vanadium source under acidic hydrothermal conditions. The borate-incorporated structure features intersecting 2D 16R channels and unusual solid-state redox properties confirmed by K-edge XANES, EPR spectral data and magnetic susceptibility measurements.
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