期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 18, 页码 3137-3139出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b927142b
关键词
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资金
- DFG [SFB-583]
- Alexander von Humboldt-Foundation
The low-valent U(III) complexes [(((t-Bu)ArO)(3)mes)U] and [(((Ad)ArO)(3)N)U] react with CO(2) to form the bridging carbonate complexes [{(((t-Bu)ArO)(3)mes)U}(2)(mu-kappa(2):kappa(2)-CO(3))] and [{(((Ad)ArO)(3)N)U}(2)(mu-eta(1):kappa(2)-CO(3))]. Uranium(IV) bridging oxo complexes have been determined to be the intermediate in these transformations.
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