期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 24, 页码 4288-4290出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00638f
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资金
- National Science Foundation [CHE-0645563, 0741973]
- Robert A. Welch Foundation [F-1621]
- Alfred P. Sloan Foundation
- Arnold and Mabel Beckman Foundation
- Division Of Chemistry [0741973] Funding Source: National Science Foundation
The synthesis and characterization of N,N'-dimesityl-4,6-diketo-5,5-dimethylpyrimidin-2-ylidene is reported; this crystalline N,N'-diamidocarbene was found to split ammonia and engage in other reactions not exhibited by typical N-heterocyclic carbenes.
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