期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 42, 页码 8046-8048出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02813d
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资金
- European community [MRTN-CT-2006-035866, THEME KBBE-2009-3-3-02, 245144]
An iridium catalysed oxidation was coupled concurrently to an asymmetric biocatalytic reduction in one-pot; thus it was shown for the first time that iridium- and alcohol dehydrogenase-catalysed redox reactions are compatible. As a model system racemic chlorohydrins were transformed to enantioenriched chlorohydrins via an oxidation-asymmetric reduction sequence.
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