期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 20, 页码 3601-3603出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c002208j
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资金
- National Natural Science Foundation of China [20732003, 20872097]
- PCSIRT [IRT0846]
- National Basic Research Program of China (973 Program) [2010CB833300]
Highly enantioselective Michael addition of malonates to beta,gamma-unsaturated alpha-ketoesters has been promoted by chiral N,N'-dioxide-Yttrium(III) complexes, providing the corresponding products in excellent yields with 94-99% ee values.
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