4.7 Article

Size dependent oxygen buffering capacity of ceria nanocrystals

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 11, 页码 1887-1889

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b923780a

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  1. EPSRC [EP/D048559/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/D048559/1] Funding Source: researchfish

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The structural, chemical and electronic changes of ceria as a function of decreasing particle size have been studied: at sizes below 5 nm the total amount of reducible oxygen dramatically increases due to superoxide formation on the ceria surface, a result indicative of a size dependent oxygen buffering capacity.

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