期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 40, 页码 7557-7559出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02023k
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- Canadian Blood Services
A cross-linked hemoglobin bis-tetramer with oxygenation properties appropriate for a red cell substitute is produced by CuAAC conjugation of a dialkyne and two equivalents of an azide of beta,beta-cross-linked hemoglobin. The latter is formed efficiently by the aminolysis of the 3,5-dibromosalicylate ester of the beta-82-beta'-82-bis trimesyl amide of human hemoglobin A with (4-aminomethyl) benzyl azide.
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