期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 44, 页码 8404-8406出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03463k
关键词
-
资金
- NSERC
- CFI
- Canada School of Energy and Environment
- GreenCentre Canada
- Alberta Ingenuity Fund
Cationic zinc complexes of a bis(phosphinimine) pincer ligand have been prepared. Methylzinc and zinc-lactate complexes have been structurally characterized, and the latter is the first cationic metal complex to promote coordination-insertion polymerization of lactide at ambient temperature. This novel catalyst system is remarkably active and also exhibits living character. A detailed investigation of the kinetics and mechanism of the polymerization process has been undertaken.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据