期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 42, 页码 7939-7941出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03113e
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资金
- National Science Foundation [CHE-1010680]
- Division Of Chemistry [1010680] Funding Source: National Science Foundation
The substantial kinetic barrier to molybdenum nitride-alkyne metathesis is facilitated by precomplexation of the borane Lewis acid B(C(6)F(5))(3), providing convenient access to metathesis-active molybdenum alkylidynes. Spectroscopic and X-ray structural analysis suggest Mo N bond weakening upon borane complexation.
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