期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 29, 页码 5223-5225出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00779j
关键词
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资金
- U.S. Department of Energy [DE-FC36-07GO17033]
- U.S. National Science Foundation [CHE-0449634]
- Argonne National Laboratory
- National Science Foundation/Department of Energy [CHE-0535644]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
Cavities up to 4 nm have been introduced into a hierarchically-assembled metal-organic framework by adopting an angular, semi-flexible tetratopic ligand. The resulting MOF possesses permanent porosity and exhibits stepwise sorption isotherms for O-2 and N-2 gases.
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