期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 20, 页码 3580-3582出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b926830h
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资金
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
The frustrated Lewis pair P(o-tolyl)(3)/B(C6F5)(3) reacts with 1,7-octadiyne by acetylene C-C coupling to yield the zwitterionic product 2a. In contrast, the P(o-tolyl)(3)/B(C6F5)(3) Lewis pair reacts with 1,6-heptadiyne by a sequence involving 1,1-carboboration of a terminal acetylene to eventually yield the heterocyclic product 4.
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