期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 8, 页码 1229-1231出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b920631k
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资金
- Japan Society for the Promotion of Science and by JST CREST [19205030]
- Japan Synchrotron Radiation Research Institute [2007A2048]
- Ministry of Education, Culture, Sports, Science and Technology
- Grants-in-Aid for Scientific Research [20111008] Funding Source: KAKEN
A lipophilic linear Fe-II complex is dispersed as nanofibers in nematic liquid crystals and displays spin-crossover at temperatures higher than those observed for the bulk crystalline state; thermal bistability is also induced in the liquid crystal environment, reflecting increased ligand field splitting energy and enhanced cooperativity by liquid crystals.
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