4.7 Article

Hydrogen-atom abstraction from methane by stoichiometric early transition metal oxide cluster cations

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 10, 页码 1736-1738

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/b924603g

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资金

  1. Chinese Academy of Sciences
  2. National Natural Science Foundation of China [20703048, 20803083, 20933008]
  3. CMS Foundation of the ICCAS [CMS-LX200902]
  4. 973 Program [2006CB932100]

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Stoichiometric early transition metal oxide cations (TiO2)(1-5)(+), (ZrO2)(1-4)(+), (HfO2)(1-2) +, (V2O5)(1-5)(+), (Nb2O5)(1-3)(+), (Ta2O5)(1-2)(+), (MoO3)(1-2)(+), (WO3)(1-3)(+), and Re2O7+ are able to activate the C-H bond of methane under near room temperature conditions.

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