期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 5, 页码 803-805出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b917004a
关键词
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资金
- Swiss National Science Foundation
- Australian Research Council
Mechanistic investigations on the previously reported reduction of B-alkylcatecholboranes in the presence of methanol led to the disclosure of a new mechanism involving catechol as a reducing agent. More than just revising the mechanism of this reaction, we disclose here the surprising role of catechol, a chain breaking antioxidant, which becomes a source of hydrogen atoms in an efficient radical chain process.
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