期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 35, 页码 6590-6592出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02233k
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资金
- Petroleum Research Fund [39923-B1]
- NIH-MBRS RISE [5R25GEMO71381]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R25GM071381] Funding Source: NIH RePORTER
A new 1,5-dipyridyl verdazyl, synthesized from the corresponding dipyridyl hydrazone, coordinates nickel(II) to form a structurally characterized, pseudooctahedral complex analogous to Ni(terpy)(2)(2+). The unusually short Ni-verdazyl distance results in strong ferromagnetic exchange (J(Ni-rad) = + 300, J(rad-rad) = + 160 cm(-1)) between all three paramagnetic species along with a metal-ligand charge transfer band in the electronic spectrum.
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