4.7 Article

Recent development of reactions with alpha-diazocarbonyl compounds as nucleophiles

期刊

CHEMICAL COMMUNICATIONS
卷 -, 期 36, 页码 5350-5361

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b908378b

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资金

  1. NSFC [20832002, 20772003, 20821062]
  2. Ministry of Education of China, and National Basic Research Program of China [2009CB825300]

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The nucleophilic addition reaction of diazo-compound derived anions or enolates with electrophilic C=O and C=N bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

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