期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 2, 页码 221-223出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b816196h
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资金
- Science Foundation Ireland
- University of Canterbury, the European Network of Excellence: MAGMANet [NMP3-CT-2005-515767]
- University of Bordeaux
- CNRS
- Region Aquitaine
- French Ministries of Foreign Affairs and of Research
Reported herein are the synthesis, structural and magnetic characterisation of a dinuclear Fe(II) triple helicate that displays an unprecedented reversible asymmetric high spin to low spin crossover characterised by a thermal hysteresis: indeed the high spin state can be recovered by white light irradiation at 10 K.
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