期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 39, 页码 5850-5852出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b910192f
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资金
- PRESTO
- GCOE (Catalysis as the Basis for Innovation in Materials Science, Hokkaido University)
Cu(I)-catalyzed anti-S(N)2'-type reduction of internal propargylic carbonates with hydrosilanes affords various di- and trisubstituted allenes with high regioselectivities; the reactions are compatible with functional groups and work efficiently for the synthesis of optically-active allenes.
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