4.7 Article

Fluorescence turn-on sensors for HSO4-

期刊

CHEMICAL COMMUNICATIONS
卷 -, 期 46, 页码 7128-7130

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b918324h

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资金

  1. SRC
  2. National Research Foundation of Korea [20090063001, KRF-2008-313-C00501]
  3. MEST [R11-2007-012-03002-0, KRF-2008-313-C00388]

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A coumarin-based derivative (1), a highly selective and sensitive turn-on fluorogenic probe for the detection of HSO4- ions in aqueous solution, has been designed and synthesized. Various spectroscopic and DFT calculations revealed that H-bonding between the phenolic -OH and imine nitrogen of 1 played a crucial role in its high selectivity for HSO4-.

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