期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 39, 页码 5907-5909出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b912267b
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资金
- JSPS
- MEXT
A general methodology applicable for the synthesis of the phoslactomycin family of antibiotics, potent and selective protein phosphatase inhibitors, has been developed starting from a beta-isocupreidine-catalyzed asymmetric Baylis-Hillman reaction of 3-(4-methoxybenzyloxy) propanal with hexafluoroisopropyl acrylate, and thereby formal syntheses of (+)-fostriecin and (+)-phoslactomycin B have been accomplished.
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