期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 23, 页码 3404-3406出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b902339a
关键词
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资金
- CNRS
- Brest and Nancy Universities
- Ministere de la Recherche
- European Union [D35-WG-0010-05/0011-05]
- Spanish Ministerio de Educacion y Ciencia [MAT2007-61584, CSD 2007-00010]
A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)(2)(tcpd)] (1) (tcpd(2-) = (C[C(CN)(2)](3))(2-), abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand.
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