期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 23, 页码 3351-3353出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b907188a
关键词
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资金
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
- Basic Energy Sciences, Department of Energy [DE-AC02-07CH11358]
The deliberate synthesis of the Keplerate [K-20 subset of {(W)W5O21(SO4)}(12)(VO)(30)(SO4)(H2O)(63)](18-) 1a with 20 pores all closed by K+ in a supramolecular fashion proves that it is possible to follow new routes in polyoxotungstate chemistry based on pentagonal {(W)W-5}-type units and to tune magnetic exchange couplings in {(M)M-5}(12)M'(30) type Keplerates.
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