4.7 Article

Ion-tagged π-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid

期刊

CHEMICAL COMMUNICATIONS
卷 -, 期 38, 页码 5734-5736

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/b906823f

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资金

  1. University of York
  2. Royal Society and Astra Zeneca
  3. EPSRC [EP/G007594/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/G007594/1] Funding Source: researchfish

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Ionic pi-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been doped into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.

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