4.7 Article

A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

期刊

CHEMICAL COMMUNICATIONS
卷 -, 期 18, 页码 2538-2540

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/b822678d

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资金

  1. Royal Society
  2. Leverhulme Trust
  3. EPSRC
  4. Johnson Matthey
  5. Engineering and Physical Sciences Research Council [EP/F013515/1] Funding Source: researchfish
  6. EPSRC [EP/F013515/1] Funding Source: UKRI

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The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)(3)}(-)] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

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