期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 12, 页码 1470-1471出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b819162j
关键词
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资金
- Mitsubishi Chemical Corporation Fund
- Sumitomo Foundation
- Ministry of Education, Culture, Sports, Science and Technology of Japan [19205013]
- Global COE Program Integrated Materials Science [B-09]
N-Sulfonyl-1,2,3-triazoles reacted with alkynes in the presence of a nickel(0)/phosphine catalyst to give substituted pyrroles, with the extrusion of molecular nitrogen; the triazole moiety isomerised to an alpha-imino diazo species, and the denitrogenative addition to nickel(0) was followed by the insertion of alkynes and reductive elimination.
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