期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 17, 页码 2381-2383出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b816910a
关键词
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资金
- UPMC Univ Paris 06
- CNRS
- DFG SPP
- [ANR-07-JCJC0045-0]
The first one-dimensional compounds where [Ln(hfac)(3)] (Ln = Gd, Tb, Dy) building blocks are bridged by a verdazyl-based radical, namely 3-imidazolyl-1,5-dimethyl-6-oxoverdazyl, were prepared and their structures elucidated; the magnetic properties were measured for all compounds and quantitatively fitted for Ln = Gd(III) using an alternate chain model leading to J(1) = -1.58 cm(-1) and to J(2) = -0.42 cm(-1).
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