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卷 41, 期 1, 页码 49-52出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(99)02039-0
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The convergent synthesis of caryophyllose, a new C-4 branched dodecose isolated from Pseudomonas caryophylli, is described from two monosaccharidic precursors. The key step is the diiodosamarium-promoted coupling of two six-carbon fragments: an acid chloride and a cyclic ketone. (C) 1999 Elsevier Science Ltd. All rights reserved.
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