4.7 Article

Apparent finite-size effects in the dynamics of supercooled liquids

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PHYSICAL REVIEW E
卷 61, 期 1, 页码 R41-R44

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AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevE.61.R41

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Molecular dynamics simulations are performed for a supercooled simple liquid with changing the system size from N = 108 to 10(4) to examine possible finite-size effects. Although almost no systematic deviation is detected in the static pair correlation functions, it is demonstrated that the structural alpha relaxation in a small system becomes considerably slower than that in larger systems for temperatures below T-c at which the size of the cooperative particle motions becomes comparable to the unit cell length of the small system. The discrepancy increases with decreasing temperature.

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