A novel chiral metal-organic framework, [Cu-2(5,5'-BDA)(2)] was synthesized by treating chiral 2,2'- dihydroxy-1,1'-binaphthalene-5,5'-dicarboxylic acid (5,5'-H(2)BDA) with a Cu(II) ion, in which the asymmetric ring opening reaction of an epoxide with amine proceeds efficiently under solvent-free conditions.
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