期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 38, 页码 4561-4563出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b808005d
关键词
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资金
- Microelectronics Advanced Research Corporation (MARCO)
- Functional Engineered NanoArchitectonics (FENA)
- Defense Advanced Research Projects Agency (DARPA)
- Center for Nanoscale Innovation for Defense (CNID)
- NSF [ECS-0609128]
The synthesis of a functionally rigid [2]rotaxane incorporating pi-electron rich 1,5-disubstituted naphthalene (NP) ring systems, encircled by the pi-electron deficient tetracationic cyclophane, cyclobis(paraquat-p-phenylene), is described; in the solid state, the molecules of this donor-acceptor [2]rotaxane line themselves up in parallel pi-pi stacks of alternating NP ring systems and bipyridinium units, a affording an interdigitated superstructure.
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