期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 14, 页码 1665-1667出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b718915j
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资金
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM062211] Funding Source: NIH RePORTER
- NIGMS NIH HHS [R01 GM062211, GM062211, R01 GM062211-07] Funding Source: Medline
We demonstrate that incorporation of MnSalen into a protein scaffold enhances the chemoselectivity in sulfoxidation of thioanisole and find that both the polarity and hydrogen bonding of the protein scaffold play an important role in tuning the chemoselectivity.
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