期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 48, 页码 6471-6488出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b812285g
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资金
- Council of Scientific & Industrial Research (CSIR)
- Department of Science & Technology (DST), Government of India
Small ring compounds represent a class of versatile building blocks in organic synthesis. Three- and four-membered ring carbo-and heterocycles are regarded as unique functional groups. Lewis acid-assisted cycloaddition of cyclopropanes, aziridines and azetidines substituted by vicinal electron-donor and electron-acceptor groups takes place in a regio- and stereocontrolled fashion. Trialkylsilylmethyl is an interesting donor substituent. In this feature article, we provide an overview of the cycloaddition of different dipolarophiles to silylmethyl-substituted small ring compounds and discuss their possible applications in synthesis.
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