4.7 Article

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

期刊

CHEMICAL COMMUNICATIONS
卷 -, 期 42, 页码 5366-5368

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b810665g

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  1. Grant-in-Aids for Young Scientists (B) [18750084]
  2. Scientific Research on Priority Areas [18032040]
  3. Ministry of Education, Culture, Sports, Science and Technology, Japan

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Allenynes having malonate-based tethers reacted with arylboronic acids in the presence of a rhodium(I) catalyst to sequentially form three carbon-carbon bonds, and arylated bicyclic skeletons were constructed in a stereoselective manner.

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