期刊
CHEMICAL BIOLOGY & DRUG DESIGN
卷 80, 期 6, 页码 821-827出版社
WILEY
DOI: 10.1111/cbdd.12053
关键词
acyl migration; ligation; molecular modeling; peptide
资金
- King Abdulaziz University [D006/431]
- University of Florida
- Kenan Foundation
Unprotected S-acylated cysteine isopeptides containing alpha-, beta- or gamma-amino acid units have been synthesized, and their conversion to native hexapeptides by S- to the N-terminus ligations involving 17-, 18- and 19-membered cyclic transition states have been demonstrated both experimentally and computationally to be more favorable than intermolecular cross-ligations.
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