期刊
CHEMICAL & PHARMACEUTICAL BULLETIN
卷 61, 期 2, 页码 245-250出版社
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.c12-00944
关键词
homophymine A; beta-hydroxy-alpha-amino acid; anti-selective asymmetric hydrogenation; Evans' asymmetric alkylation
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan
For the total synthesis of novel cyclodepsipeptide homophymine A, (2R,3R,4R)-2-amino-3-hydroxy-4,5-dimethylhexanoic acid was successfully synthesized by Evans' asymmetric alkylation and the anti-selective asymmetric hydrogenation of a chiral alpha-amino-beta-keto ester as the key steps.
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