期刊
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
卷 -, 期 19, 页码 3473-3479出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b002554m
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The first bidentate, peralkylated guanidine based ligand has been synthesized and its complexation chemistry examined by the preparation of three representative coordination compounds. The novel chelate ligand 1,3-bis(N,N,N',N'-tetramethylguanidino)propane (btmgp, 1) has been synthesized by the reaction of N,N,N',N'-tetramethylguanidine (TMG) with 1,3-dibromopropane and subsequent deprotonation of the resulting guanidinium salt with sodium ethoxide. The bifunctional N-donor compound was treated with copper(I) iodide, copper(II) chloride and iron(II) iodide in a 1 : 1 molar ratio to yield the corresponding electroneutral complexes [CuI(btmgp)] 2, [CuCl2(btmgp)] 3 and [FeI2(btmgp)] 4. The structures of the dihydrochloride of 1 (1b) and of the complexes 2-4 have been determined by X-ray crystallography. A comparison of the molecular structures (2-4) shows that, in each case, btmgp acts as a bidentate ligand which is able to stabilize not only trigonal-planar (2), but also (distorted) square-planar (3) and tetrahedral coordination environments (4).
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