期刊
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
卷 -, 期 3, 页码 353-359出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/a907545c
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Using sterically hindered 2,9-diarylphenanthrolines (I) as well as unsubstituted or 4,7-disubstituted phenanthrolines (II) the first preparation of open chain heteroleptic bis(phenanthroline) complexes [M(I)(II)](n+) with M=Ag+ or Zn2+ has been realised. Their structure was confirmed by electrospray MS, NMR and in one case X-ray data. With two sets of phenanthroline ligands, three stereoisomers of [M(I)(II)](+) were detected in the silver(I) and for comparative reasons in the corresponding copper(I) complexes. On the basis of NMR experiments these were assigned as in-in, in-out and out-out isomers.
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