期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 83, 期 1, 页码 29-32出版社
AMER CERAMIC SOC
DOI: 10.1111/j.1151-2916.2000.tb01143.x
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The synthesis of a black Fe2O3-Cr2O3 pigment has been studied to better understand the synthesis mechanism. A mechanism is proposed according to which, under the tested operating conditions, one of the starting constituents (Cr2O3) is transferred, largely in a gas phase (after subliming), to the particle surface of the other constituent (Fe2O3), at which it is deposited or chemisorbed, forming a layer from which it diffuses inward into the Fe2O3 particles. The process stops when the composition of the resulting solid solution has became uniform.
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