期刊
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
卷 -, 期 15, 页码 2465-2473出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b001721n
关键词
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A novel methodology for asymmetric synthesis of 2-amino-2-deoxy sugars is developed, starting from readily available chiral building block 1 and 2,3-O-isopropylideneglyceraldehyde 2, via Julia olefination and subsequent dihydroxylation as key steps. The versatility of this approach is exemplified by the preparation of L-glucosamine, L-mannosamine and L-talosamine derivatives in highly diastereometrically pure forms.
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