期刊
ELECTROCHIMICA ACTA
卷 45, 期 21, 页码 3573-3579出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0013-4686(00)00481-3
关键词
electrochemical electrode; rotating disk electrode; enzyme
The electrochemical oxidation of H2O2 at platinum rotating disc electrodes and microelectrodes was studied in the presence of chloride in the range 0-120 mM at pH 7.3. Oxidation was inhibited by chloride with greater inhibition at higher electrode rotation rates. The mode of inhibition was deduced to be non-competitive with the chloride interacting with precursor binding sites at the electrode surface, since increased [H2O2] did not decrease the degree of inhibition. The rotation rate dependence indicates that it is likely a soluble platinum complex involving chloride forms to remove binding sites from the electrode surface. (C) 2000 Elsevier Science Ltd. All rights reserved.
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